Electronic structure and properties of transition metal compounds

introduction to the theory by I. B. Bersuker

Publisher: Wiley in Hoboken, N.J

Written in English
Published: Pages: 759 Downloads: 190
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Edition Notes

Includes bibliographical references and indexes.

StatementIsaac B. Bersuker
Classifications
LC ClassificationsQD172.T6 B48 2010
The Physical Object
Paginationxxxvi, 759 p. :
Number of Pages759
ID Numbers
Open LibraryOL24519834M
ISBN 100470180234
ISBN 109780470180235
LC Control Number2009021658
OCLC/WorldCa230180467

Electronic structure and properties of transition metal compounds by I. B. Bersuker Download PDF EPUB FB2

Electronic Structure and Properties of Transition Metal Compounds: Introduction to the Theory, Second Edition. Author(s): About this book. spectroscopic and magnetic properties, methods of electronic structure calculation, and quantum-classical modeling for organometallic and metallobiochemical systems.

Electronic structure and properties of transition metal compounds: introduction to the theory / Isaac B. Bersuker. – 2nd ed. – (Textbook for graduate and advanced undergraduate students) Includes bibliographical references and index. ISBN (cloth) 1. Transition metal compounds. Title. QDT6B48 Electronic Structure and Properties of Transition Metal Compounds: Introduction to the Theory (2) Electronic structure and properties of transition metal compounds book larger image.

spectroscopic and magnetic properties, methods of electronic structure calculation, and quantum-classical modeling for organometallic and metallobiochemical systems.

Book Details Book Quality: Publisher Quality ISBN Transition metal compounds containing bonds to zinc, cadmium, or mercury have been known for quite some time, the first such compound, Fe(CO) 4 (HgCl) 2, being reported in 1 It was not until the late s, however, that broadly applicable synthetic methods were developed for forming bonds between the group 12 elements and a wide range of transition metal moieties.

Get this from a library. Electronic structure and properties of transition metal compounds: introduction to the theory. [I B Bersuker] -- "With more than 40% new and revised materials, this second edition offers researchers and students in the field a comprehensive understanding of fundamental molecular properties amidst cutting-edge.

Get this from a library. Electronic structure and properties of transition metal compounds: introduction to the theory. [I B Bersuker] -- Covering all the latest developments, and applying the theory of electronic structure to problem solving at every opportunity, Electronic Structure and Properties of Transition Metal Compounds places.

With more than 40% new and revised materials, this second edition offers researchers and students in the field a comprehensive understanding of fundamental molecular properties amidst cutting-edge applications.

Including ~70 Example-Boxes and summary notes, questions, exercises, problem sets, and illustrations in each chapter, this publication is also suitable for use as a textbook for.

Properties and Trends in Transition Metals. The elements of the second and third rows of the Periodic Table show gradual changes in properties across the table from left to right as expected. Electrons in the outer shells of the atoms of these elements have little shielding effects resulting in an increase in effective nuclear charge due to the addition of protons in the nucleus.

The book focuses on the electronic structure and related properties of coordination compounds, essentially treating chemical bonding as an electronic phenomenon. It also covers the central concepts of quantum chemistry and atomic states, examines theories of electronic structure and vibronic coupling, and explores physical methods of investigation.

This book presents the results of investigations into the magnetic properties of 3d-transition metal compounds. In particular, it deals with 3d-metal pnictides (i.e., compounds containing phosphorus, arsenic, antimony or bismuth). Part I reports the experimental data together with.

Electronic Structure and Properties of Transition Metal Compounds: Introduction to the Theory. by Isaac B. Bersuker English | | ISBN: | pages | PDF | MB. Disorder induced effects on electronic structure of transition metal oxides Electronic and magnetic properties of transition metal compounds in general and oxides in particular have been topics of great interest for many decades in view of their wide ranging properties.

the electronic structure of such systems are conventionally Author: D.D. Sarma. Transition metal compounds are manifestly the main area of interest and the basis for a large field of physical phenomena: the physics of systems with strong electron correla-tions.

Many novel ideas, such as Mott insulators, were first suggested and developed in application to transition metal compounds. Electronic Structure and Properties of Transition Metal Compounds: Introduction to the Theory; Spin Crossover in Transition Metal Compounds III by Philipp Gütlich; Handbook of Semiconductor Technology Electronic Structure and Properties of Semiconductors, Volum.

Band Gaps and Electronic Structure of Transition-Metal Compounds Article (PDF Available) in Physical Review Letters 55(4) August with Reads How we measure 'reads'. The following sections are included: * Introduction * Electronic Structure: Basic Concepts * Band Gaps and Systematic * Multiplets and Ligand Fields * Crystal (Ligand) Field Splittings * Hybridization/Covalency * Parameter estimates for the TM oxides * Superexchange and Cu-O Exchange * Model Hamiltonian Parameters for the High Tc superconductors * Influence of Doping or Non Author: G.

Sawatzky. The present book is not primarily about Tc superconductors, although their main properties are discussed in the final sections. The main aim is to describe the varied electronic behaviour shown by transition metal oxides, and to discuss the different types of theoretical models that have been proposed to interpret this behaviour."--pub.

desc. The compounds of transition metals with oxygen and other elements of group 16 have an exceedingly diverse range of electronic properties. They include wide bandgap insulators, semiconductors, metals, and superconductors.

Associated with their electronic structure are other properties such as magnetic and optical ones that find important Cited by: 2. This innovative text offers basic understanding of the electronic structure of covalent and ionic solids, simple metals, transition metals and their compounds.

It also explains how to calculate dielectric, conducting, and bonding properties for each. Includes a useful Solid State Table of the Elements. The book includes all main physical properties of d- and f-transition-metal systems and corresponding theoretical concepts.

Especial attention is paid to the theory of magnetism and transport phenomena. Some examples of non-traditional questions which are treated in detail in the book: the influence of density of states singularities on electron properties; many-electron description of strong.

"Should be widely read by practicing physicists, chemists and materials scientists." — Philosophical MagazineIn this comprehensive and innovative text, Professor Harrison (Stanford University) offers a basic understanding of the electronic structure of covalent and ionic solids, simple metals, transition metals, and their compounds.

The book. Transition Metal Impurities in Semiconductors: Electronic Structure and Physical Properties; Transition Metal Impurities in Semiconductors: Electronic Structure and Physical Properties; [PDF] Electronic Structure and Properties of.

The text covers covalent semiconductors, ionic insulators, simple metals, and transition-metal and f-shell-metal systems. It focuses on the most important aspects of each system, making what approximations are necessary in order to proceed analytically and obtain formulae for the properties.

This innovative text offers basic understanding of the electronic structure of covalent and ionic solids, simple metals, transition metals and their compounds. It also explains how to calculate dielectric, conducting, and bonding properties for each. It includes a useful Solid State Table of the Elements.

Show less. Electronic (Absorption) Spectra of 3d Transition Metal Complexes 7 degeneracy, ML, is given by (2L+1) running from L to example, L= 2 for D state and so the orbital degeneracy is (2x2+1) =5 Size: KB. Electronic Structure and Properties of Transition Metal Compounds - ISBN: - (ebook) - von Isaac B.

Bersuker, Verlag: Wiley. Overview of Transition Metal Complexes. coordinate covalent or dative bond applies bases are called LIGANDS—all serve as σ-donors some are π-donors as well, and some are π-acceptors 3. Specific coordination number and geometries depend on metal and number of d File Size: KB.

In this contribution, we describe fundamental electronic structures and spin-charge-orbital orderings of 5d transition-metal compounds. By reviewing photoemission spectroscopy studies on CuIr 2 S 4, IrTe 2, Cs 2 Au 2 Br 6, and AuTe 2, we discuss the difference between the t 2g and e g systems with respect to the spin-orbit splitting versus the Jahn-Teller by: 2.

The redox behavior, magnetic and optical properties of the transition elements are important features underlying their use in innumerable applications.

We shall be dealing with the electronic configurations, general characteristics, and complex forming tendency of transition elements. Atomic Structures and Properties Electronic configurationsFile Size: 1MB. In LitRes digital library you can download the book Electronic Structure and Properties of Transition Metal Compounds.

Introduction to the Theory by Isaac Bersuker B. Read reviews of the book and write your own at LitRes!. Transition metal oxides form a series of compounds with a uniquely wide range of electronic properties.

They have important applications as dielectrics, semiconductors, and metals, and as materials for magnetic and optical uses. The recent Pages: We have studied a wide range of 3d transition-metal compounds by a cluster configuration-interaction analysis of the metal 2p core-level photoemission spectra.

Deduced values for the charge-transfer energy Δ and the d-d Coulomb repulsion U, defined with respect to the multiplet-averaged energies, show a smooth variation as functions of cation Cited by: Electronic Structure and Properties of Transition Metal Compounds Bersuker I.B.

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